案例索引

代表性案例总索引

下表保留前述调研中的全部 20 个主要案例，并给出其主要归属。部分实例同时涉及两条物理主线，这里按最核心的 W-band 信息来源归类。

编号	体系 / 科学问题	主要主线	代表文献
1	Photosynthetic semiquinone $$g$$ tensor	1. $$g$$ 分辨	Burghaus et al., 1993, 10.1021/j100131a037
2	Flavin radical tensor orientation / ENDOR	3. 取向选择	Kay et al., 2005, 10.1021/ja051572s
3	Nitroxide solvent polarity / H-bond response	4. 动力学与环境	Owenius et al., 2001, 10.1021/jp0116914
4	Protein local electrostatics / p $$K_a$$	4. 动力学与环境	Voinov et al., 2008, 10.1021/bi800272f
5	IDP fast rotational dynamics	4. 动力学与环境	Casey et al., 2014, 10.1016/j.bbrc.2014.06.045
6	Azurin Type-I Cu full $$g$$ tensor	1. $$g$$ 分辨	10.1021/ja00086a044
7	Cu $$_A$$ ligand hyperfine / ENDOR	3. 取向选择	10.1021/ja003924v
8	Aqueous vanadyl electronic structure	1. $$g$$ 分辨	10.1021/jp992186y
9	Cr/Mo M–M bonded orbital character	1. $$g$$ 分辨	10.1021/ic0260670
10	Fe $$_4$$ single-molecule magnet anisotropy	2. ZFS / high-spin	10.1021/jp003441d
11	High-spin nitrene ZFS sign	2. ZFS / high-spin	10.1021/acs.jpca.2c04211
12	Yb $^{3+}$ :CaWO $$_4$$ coherent spin manipulation	5. 量子自旋	Rakhmatullin et al., 2009, 10.1103/PhysRevB.79.172408
13	Gd-doped glass central-transition / clustering	2. ZFS / high-spin	Smirnov & Sen, 2001, 10.1063/1.1403436
14	Gd $^{17}$ O ENDOR / water coordination	3. 取向选择	10.1021/jp040306i
15	Mn $^{2+}$ -EDTA protein DEER	3. 取向与距离	Banerjee et al., 2012, 10.1021/jz201521d
16	Radical-pair orientation-resolved dipolar EPR	3. 取向与距离	10.1021/jp401573z
17	Cr $$_7$$ Ni / Co coupled molecular qubits	5. 量子自旋 / exchange	Ferrando-Soria et al., 2016, 10.1038/ncomms11377
18	MgO surface trapped-electron centers	1. $$g$$ 分辨 / defect	Rocker et al., 2014, 10.1063/1.4893729
19	Silicon FET donor / 2DEG EDMR	1 & 5. defect / high-field readout	Lang et al., 2011, 10.1063/1.3557395；Lo et al., 2011, 10.1103/PhysRevLett.106.207601
20	6H- $^{28}$ SiC defect coherence	5. 量子自旋	Murzakhanov et al., 2024, 10.1063/5.0222098

编号	体系 / 科学问题	主要主线	代表文献
1	Photosynthetic semiquinone $\(g\)$ tensor	1. $\(g\)$ 分辨	Burghaus et al., 1993, 10.1021/j100131a037
2	Flavin radical tensor orientation / ENDOR	3. 取向选择	Kay et al., 2005, 10.1021/ja051572s
3	Nitroxide solvent polarity / H-bond response	4. 动力学与环境	Owenius et al., 2001, 10.1021/jp0116914
4	Protein local electrostatics / p $\(K_a\)$	4. 动力学与环境	Voinov et al., 2008, 10.1021/bi800272f
5	IDP fast rotational dynamics	4. 动力学与环境	Casey et al., 2014, 10.1016/j.bbrc.2014.06.045
6	Azurin Type-I Cu full $\(g\)$ tensor	1. $\(g\)$ 分辨	10.1021/ja00086a044
7	Cu $\(_A\)$ ligand hyperfine / ENDOR	3. 取向选择	10.1021/ja003924v
8	Aqueous vanadyl electronic structure	1. $\(g\)$ 分辨	10.1021/jp992186y
9	Cr/Mo M–M bonded orbital character	1. $\(g\)$ 分辨	10.1021/ic0260670
10	Fe $\(_4\)$ single-molecule magnet anisotropy	2. ZFS / high-spin	10.1021/jp003441d
11	High-spin nitrene ZFS sign	2. ZFS / high-spin	10.1021/acs.jpca.2c04211
12	Yb $^{3+}$ :CaWO $\(_4\)$ coherent spin manipulation	5. 量子自旋	Rakhmatullin et al., 2009, 10.1103/PhysRevB.79.172408
13	Gd-doped glass central-transition / clustering	2. ZFS / high-spin	Smirnov & Sen, 2001, 10.1063/1.1403436
14	Gd $^{17}$ O ENDOR / water coordination	3. 取向选择	10.1021/jp040306i
15	Mn $^{2+}$ -EDTA protein DEER	3. 取向与距离	Banerjee et al., 2012, 10.1021/jz201521d
16	Radical-pair orientation-resolved dipolar EPR	3. 取向与距离	10.1021/jp401573z
17	Cr $\(_7\)$ Ni / Co coupled molecular qubits	5. 量子自旋 / exchange	Ferrando-Soria et al., 2016, 10.1038/ncomms11377
18	MgO surface trapped-electron centers	1. $\(g\)$ 分辨 / defect	Rocker et al., 2014, 10.1063/1.4893729
19	Silicon FET donor / 2DEG EDMR	1 & 5. defect / high-field readout	Lang et al., 2011, 10.1063/1.3557395；Lo et al., 2011, 10.1103/PhysRevLett.106.207601
20	6H- $^{28}$ SiC defect coherence	5. 量子自旋	Murzakhanov et al., 2024, 10.1063/5.0222098